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Europium fluoride (II)

Europium (II) fluoride is a binary inorganic compound, a salt of europium metal and hydrofluoric acid with the formula EuF 2 , light yellow crystals, it does not dissolve in water.

Europium fluoride
Are common
Systematic
name
Europium fluoride
Traditional namesEuropium fluoride
Chem. formulaEuF 2
Physical properties
conditionlight yellow crystals
Molar mass189.96 g / mol
Density6.5 g / cm³
Thermal properties
T. melt.≈1380; 1403; 1416 ° C
Classification
Reg. CAS number14077-39-5
Reg. EINECS number

Content

Getting

  • Recovery of europium (III) fluoride with metallic europium:
2EuF3+Eu→950oC3EuF2{\ displaystyle {\ mathsf {2EuF_ {3} + Eu \ {\ xrightarrow {950 ^ {o} C}} \ 3EuF_ {2}}}}  
  • Reduction of europium (III) fluoride with hydrogen :
2EuF3+H2→1100oC2EuF2+2HF{\ displaystyle {\ mathsf {2EuF_ {3} + H_ {2} \ {\ xrightarrow {1100 ^ {o} C}} \ 2EuF_ {2} + 2HF}}}  

Physical Properties

Europium (II) fluoride forms light yellow crystals of cubic syngony , space group F m3m , cell parameters a = 0.58423 nm, Z = 4.

Not soluble in water.

Antiferromagnet ; Curie temperature 2 K [1] .

Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Greenwood N., Earnshaw A. Chemistry of elements. - Binom. Laboratory of knowledge, 2008. - T. 2. - 666 p. - ISBN 978-5-94774-372-2 .
  • CRC Handbook of Chemistry and Physics . - 89th Edition. - Taylor and Francis Group, LLC, 2008-2009.

Notes

  1. ↑ McGuire TR, Shafer MW Ferromagnetic Europium Compounds // Journal of Applied Physics. - 1964. - Vol. 35. - P. 984–988. - ISSN 00218979 . - DOI : 10.1063 / 1.1713568 .


Source - https://ru.wikipedia.org/w/index.php?title=Europe fluoride ( II)&oldid = 94185612


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