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Gallium Selenide (II)

Gallium (II) selenide is a binary inorganic compound of gallium and selenium with the formula GaSe, red-brown crystals that are not soluble in water.

Gallium selenide
The dark red Gallium Selenid in its bulk form.jpg
Are common
Systematic
name
Gallium Selenide (II)
Traditional namesGallium selenium
Chem. formulaGase
Physical properties
conditionred brown crystals
Molar mass148.68 g / mol
Density5.03 g / cm³
Thermal properties
T. melt.960 ° C
Chemical properties
Solubility in waternot soluble
Classification
Reg. CAS number12024-11-2
PubChem
Reg. EINECS number
Smiles
Inchi
ChemSpider

Getting

  • Fusion of gallium and selenium:
Ga+Se→960oCGaSe{\ displaystyle {\ mathsf {Ga + Se \ {\ xrightarrow {960 ^ {o} C}} \ GaSe}}} {\displaystyle {\mathsf {Ga+Se\ {\xrightarrow {960^{o}C}}\ GaSe}}}

Physical Properties

Gallium (II) selenide forms red-brown crystals of two modifications:

  • hexagonal syngony, space group P 6 , cell parameters a = 0.373 nm, c = 1.588 nm, Z = 4;
  • trigonal syngonium, space group R 3m , cell parameters a = 0.3739 nm, c = 2.3862 nm, Z = 6.

There is evidence of two more crystalline modifications.

It has semiconductor properties.

Application

  • Used in photodiodes , polarized radiation sensors, photoresistors .

Literature

  • Chemical Encyclopedia / Editorial Board: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1988. - T. 1. - 623 p.
  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Greenwood N., Earnshaw A. Chemistry of elements. - Binom. Laboratory of Knowledge, 2008. - T. 1. - 608 p. - ISBN 978-5-94774-373-9 .
  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower, G. - M .: Mir, 1985 .-- T. 3 .-- 392 p.
  • Chemistry and Technology of Rare and Scattered Elements, Part I / Ed. K.A. Bolshakova. - M .: Higher. School, 1976 .-- 368 p.
  • Atomic diffusion in semiconductor structures. G. B. Abdullaev et al. Atomizdat. Moscow., 1980



Source - https://ru.wikipedia.org/w/index.php?title=Gallium_Selenide(II)&oldid=95291710


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