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Gallium bromide (II)

Gallium (II) bromide is an inorganic compound, a salt of gallium and hydrobromic acid with the formula GaBr 2 , colorless crystals, reacts with water .

Gallium bromide
Are common
Systematic
name
Gallium bromide (II)
Traditional namesGallium bromide
Chem. formulaGaBr 2
Physical properties
conditioncolorless crystals
Molar mass229.54 g / mol
Density3.4711 166 g / cm³
Thermal properties
T. melt.166; 166.7 ° C
T. sub.200 ° C
T. bale.462 ° C
Chemical properties
Solubility in benzenedissolves
Classification
Reg. CAS number
PubChem
Smiles
Inchi
ChemSpider

Content

Getting

  • The reaction of gallium and gallium (III) bromide in vacuum:
G a B r 3 + G a → 180 o C 2 G a B r 2{\ displaystyle {\ mathsf {GaBr_ {3} + Ga \ {\ xrightarrow {180 ^ {o} C}} \ 2GaBr_ {2}}}}  

Physical Properties

Gallium (II) bromide forms colorless diamagnetic spreading crystals. The real formula of the substance is Ga [GaBr 4 ]. The melt conducts an electric current and contains Ga + and [GaBr 4 ] - ions. It is soluble in benzene and toluene , the solution conducts an electric current.

Chemical Properties

  • Reacts with water:
6GaBr2+6H2O→fourGaBr3+2Ga(OH)3+3H2↑{\ displaystyle {\ mathsf {6GaBr_ {2} + 6H_ {2} O \ {\ xrightarrow {}} \ 4GaBr_ {3} + 2Ga (OH) _ {3} + 3H_ {2} \ uparrow}}}  
  • Disproportionate when heated:
3GaBr2→>300oC2GaBr3+Ga{\ displaystyle {\ mathsf {3GaBr_ {2} \ {\ xrightarrow {> 300 ^ {o} C}} \ 2GaBr_ {3} + Ga}}}  

Literature

  • Chemical Encyclopedia / Editorial Board: Knunyants I. L. et al. - M .: Soviet Encyclopedia, 1988. - T. 1. - 623 p.
  • Handbook of a chemist / Editorial: Nikolsky B.P. et al. - 3rd ed., Rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Greenwood N., Earnshaw A. Chemistry of elements. - Binom. Laboratory of Knowledge, 2008. - T. 1. - 608 p. - ISBN 978-5-94774-373-9 .
  • Inorganic Synthesis Guide: 6 Vol. / Ed. Brower, G. - M .: Mir, 1985 .-- T. 3 .-- 392 p.
  • Chemistry and Technology of Rare and Scattered Elements, Part I / Ed. K.A. Bolshakova. - M .: Higher. School, 1976 .-- 368 p.



Source - https://ru.wikipedia.org/w/index.php?title= Gallium bromide ( II)&oldid = 82558816


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