Vanadium Sulfide

Vanadium sulfide - a binary inorganic compound, a metal salt of vanadium and hydrogen sulfide acid with the formula VS, black-brown crystals.

Getting

{\mathsf {V_{2}S_{3}\ {\xrightarrow {850-950^{o}C,\tau }}\ 2VS+S}}

{\ displaystyle {\ mathsf {V_ {2} S_ {3} \ {\ xrightarrow {850-950 ^ {o} C, \ tau}} \ 2VS + S}}}

{\mathsf {V_{2}S_{3}+H_{2}\ {\xrightarrow {850-1100^{o}C,\tau }}\ 2VS+H_{2}S}}

{\ displaystyle {\ mathsf {V_ {2} S_ {3} + H_ {2} \ {\ xrightarrow {850-1100 ^ {o} C, \ tau}} \ 2VS + H_ {2} S}}}

{\mathsf {2V_{2}O_{5}+9S\ {\xrightarrow {400^{o}C}}\ 4VS+5SO_{2}}}

{\ displaystyle {\ mathsf {2V_ {2} O_ {5} + 9S \ {\ xrightarrow {400 ^ {o} C}} \ 4VS + 5SO_ {2}}}}

Vanadium sulfide forms black-brown crystals of hexagonal syngony , space group P 6 / mmc , cell parameters a = 0.334 nm, c = 0.5785 nm, Z = 2.

{\mathsf {4VS+9O_{2}\ {\xrightarrow {T}}\ 2V_{2}O_{5}+4SO_{2}}}

{\ displaystyle {\ mathsf {4VS + 9O_ {2} \ {\ xrightarrow {T}} \ 2V_ {2} O_ {5} + 4SO_ {2}}}}

Chemical Encyclopedia / Editorial Board: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1988. - T. 1. - 623 p.
Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1972. - T. 2. - 871 p.