Oxide fibers ( English oxide fibers ) - structural fibers containing oxides as the main component.
Description
Two types of oxide fibers are known, mainly used as a reinforcing agent for high-temperature composites - single-crystal and eutectic threads and rods, as well as nanostructured threads. The first type of fiber is obtained by melt crystallization by methods based on the Stepanov concept (EFG (Edge-defined Film-fed Growth) and micropulling-down), LHPG (Laser Heated Pedestal Growth), as well as internal crystallization. The second type of fiber is produced using procedures traditional for powder metallurgy (slip, sol-gel ).
Single crystal and eutectic fibers are stable at high temperatures and are characterized by high creep resistance (creep resistance). For example, the fibers of mullite (2Al 2 O 3 ∙ SiO 2 ) and yttrium-aluminum garnet (YAG, Y 3 Al 5 O 12 ) are creep-resistant at temperatures up to 1600 ° С.
Polycrystalline fibers recrystallize at high temperatures and lose their initial nanocrystalline structure at temperatures of 1100–1300 ° С, depending on the composition and exposure time. The most creep-resistant of them, which are a mixture of mullite and alumina, can be used for a long time at temperatures up to 1300 ° C.
Oxide fibers are used in composites with nickel and oxide matrices. Inexpensive fibers that are not distinguished by high strength can be used as thermal insulation.
Literature
- Concise Encyclopedia of Composite Materials / Ed. by A. Kelly. - Elsevier Science, 1994 .-- 378 p.
- Chawla KK Fibrous Materials. - Cambridge University Press, 1998 .-- 309 p.
- Handbook of Composites. V. 1: Strong Fibers / Ed. by W. Watt, BV Petrov. - NY: Elsevier, 1989.
- Mileiko S. T., Serebryakov A. V., Kiyko V. M. et al. Single-crystal mullite fibers obtained by internal crystallization // Composites and Nanostructures. 2009. No. 2. S. 47-60.
- Mileiko ST Single crystalline oxide fibers for heat-resistant composites // Compos. Sci. and Technol. 2005. V. 65, No. 15-16. P. 2500-2513.