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Diforamine

Diforamine is an inorganic compound, a fluorine derivative of ammonia with the formula NHF 2 , a colorless gas, explosive in liquid and solid states.

Diforamine
Are common
Systematic
name
Diforamine
Chem. formulaNHF 2
Physical properties
conditioncolorless gas
Molar mass53.01 g / mol
Densityg. 1.378 -23.6 g / cm³
Thermal properties
T. melt.-116.8 ° C
T. bale.-23.3 ° C
T. decomp.20 ° C
Like heat resistant.43.38 J / (mol · K)
Enthalpy of Education-103 kJ / mol
Structure
Dipole moment1.93 D
Classification
Reg. CAS number
PubChem
Smiles
Inchi
ChemSpider

Getting

  • Fluorination of urea solutions:
fourF2+(NH2)2CO→(NF2)2CO+fourHF{\ displaystyle {\ mathsf {4F_ {2} + (NH_ {2}) _ {2} CO \ {\ xrightarrow {}} \ (NF_ {2}) _ {2} CO + 4HF}}}  
followed by hydrolysis of the products:
(NF2)2CO+H2O→2NHF2+CO2{\ displaystyle {\ mathsf {(NF_ {2}) _ {2} CO + H_ {2} O \ {\ xrightarrow {}} \ 2NHF_ {2} + CO_ {2}}}}  

Physical Properties

Diforamine forms a colorless gas, and when liquefied, it forms a colorless liquid.

It is soluble in water and diethyl ether .

In liquid and solid state it is explosive.

Literature

  • Chemical Encyclopedia / Editorial Board: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1988. - T. 1. - 623 p.
  • Greenwood N., Earnshaw A. Chemistry of elements. - Binom. Laboratory of Knowledge, 2008. - T. 1. - 608 p. - ISBN 978-5-94774-373-9 .


Source - https://ru.wikipedia.org/w/index.php?title= Diforamine&oldid = 80364940


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