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Yttrium acetylacetonate

Yttrium acetylacetonate is an organic substance , a chelate compound of yttrium metal with the formula Y (С 5 H 7 O 2 ) 3 . Under normal conditions, it is a white solid that is readily soluble in water and organic solvents.

Yttrium acetylacetonate
Are common
Systematic
name
Yttrium acetylacetonate
Chem. formulaY (С 5 H 7 O 2 ) 3
Rac formulaYC 15 H 21 O 6
Physical properties
conditionwhite solid
Molar mass386.066 g / mol
Density1,403 g / cm³
Thermal properties
T. melt.133 ° C

Content

Getting

  • The interaction of aqueous solutions of yttrium salts with an alcohol solution of acetylacetone :
YCl3+3CfiveHeightO2→C2HfiveOH,pH=6,2Y(CfiveH7O2)3+3HCl{\ displaystyle {\ mathsf {YCl_ {3} + 3C_ {5} H_ {8} O_ {2} \ {\ xrightarrow {C_ {2} H_ {5} OH, pH = 6.2}} Y (C_ {5} H_ {7} O_ {2}) _ {3} + 3HCl}}}  

Physical Properties

Yttrium acetylacetonate forms a white solid with a density of 1.403 g / cm 3 , dissolves well in water, ethers, carbon disulfide , carbon tetrachloride , benzene , etc. Melts at 133 ° C.

Chemical Properties

Forms numerous adducts :

Adduct, formulaCondition (nos)Melting point, ° С
Y (С 5 H 7 O 2 ) 3 · NH 3white crystals129
Y (С 5 H 7 O 2 ) 3 · С 5 H 5 Nwhite needles121
Y (С 5 H 7 O 2 ) 3 · С 6 H 5 NH 2white crystals109
Y (C 5 H 7 O 2 ) 3 · CH 3 -CNWhite powder138

Literature

  • Ripan R., Chetyanu I. Inorganic chemistry. Metal Chemistry. - M .: Mir, 1972. - T. 2. - 871 p.
Source - https://ru.wikipedia.org/w/index.php?title=Acetylacetonate_ittrium&oldid=80360512


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Clever Geek | 2019