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Trimedium phosphide

Trimedium phosphide is an inorganic compound of a metal of copper and phosphorus with the formula Cu 3 P, gray-black crystals, does not dissolve in water.

Trimedium phosphide
Are common
Systematic
name
Trimedium phosphide
Traditional namesPhosphor copper
Chem. formulaCu 3 P
Physical properties
conditiongray-black crystals
Molar mass221.61 g / mol
Density6.4-6.8; 7.09 g / cm³
Thermal properties
T. melt.1030 ° C
Classification
Reg. CAS number12019-57-7
PubChem
Reg. EINECS number
Smiles
Inchi
ChemSpider

Getting

  • Heating of copper and red phosphorus:
3 C u + P → T C u 3 P{\ displaystyle {\ mathsf {3Cu + P \ {\ xrightarrow {T}} \ Cu_ {3} P}}}  
  • Reduction of dimedi phosphide with hydrogen :
6Cu2P+3H2→1000oCfourCu3P+2PH3{\ displaystyle {\ mathsf {6Cu_ {2} P + 3H_ {2} \ {\ xrightarrow {1000 ^ {o} C}} \ 4Cu_ {3} P + 2PH_ {3}}}}  

Physical Properties

Trimedium phosphide forms gray-black crystals (according to other sources, copper-colored crystals), trigonal system , space group P 3 c1 , cell parameters a = 0.6940 nm, c = 0.7135 nm, Z = 6.

Not soluble in water.

Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1972. - T. 2. - 871 p.



Source - https://ru.wikipedia.org/w/index.php?title= Trimedium Phosphide&oldid = 80372357


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