Diethyltin is an organometallic compound of tin with the formula Sn (C 2 H 5 ) 2 . Under normal conditions, it is a yellow liquid, poorly soluble in water , but soluble in organic solvents.
Diethyl tin | |
---|---|
Are common | |
Systematic name | Diethyl tin |
Chem. formula | Sn (C 2 H 5 ) 2 |
Rac formula | SnC 4 H 10 |
Physical properties | |
condition | yellow liquid |
Molar mass | 177 g / mol |
Thermal properties | |
T. Kip. | 150 ° C |
Classification | |
Pubchem | |
SMILES | |
Inchi | |
Chemspider | |
Content
Getting
- Effect of ethylmagnesium bromide on tin dichloride :
- {\ displaystyle {\ mathsf {SnCl_ {2} + 2Mg (C_ {2} H_ {5}) Br \ {\ xrightarrow {}} \ Sn (C_ {2} H_ {5}) _ {2} + MgCl_ { 2} + MgBr_ {2}}}}
- Recovery of diethyltin chloride by zinc :
Physical Properties
Diethyl tin is a yellow liquid, almost insoluble in water, but soluble in organic solvents . Boils at a temperature of about 150 ° C, with further heating decomposes.
Chemical Properties
- Reacts with chlorine :
- Oxidized on the air:
- Decomposition occurs with the formation of tetraethyl tin :
- Interacts with chloroethane :
Literature
- Chemical Encyclopedia / Redkol .: Knunyants I.L. et al. - Moscow : Soviet Encyclopedia , 1992. - Vol. 3. - 639 p. - ISBN 5-82270-039-8 .
- Chemist Handbook / Redkol .: Nikolsky B.P. et al. - 2nd ed., Rev. - M.-L.: Chemistry , 1966. - T. 1. - 1072 p.
- Chemist Handbook / Redkol .: Nikolsky B.P. et al. - 3rd ed., Rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
- Lidin R.A. and other Chemical properties of inorganic substances: Proc. manual for universities. - 3rd ed., Corr. - M .: Chemistry, 2000. - 480 p. - ISBN 5-7245-1163-0 .
- Ripan R., Chetyanu I. Inorganic chemistry. Metal Chemistry. - M .: Mir , 1972. - T. 2. - 871 p.