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Palladium iodide (II)

Palladium (II) iodide is an inorganic compound, a salt of palladium metal and hydroiodic acid with the formula PdI 2 , dark red crystals, does not dissolve in water.

Iodide palladium
Are common
Systematic
name
Palladium iodide (II)
Traditional namesPalladium Iodide
Chem. formulaPDI 2
Physical properties
conditiondark red crystals
Molar mass360.2 g / mol
Thermal properties
T. decomp.350 ° C
Enthalpy of Education-63 kJ / mol
Classification
Reg. CAS number7790-38-7
PubChem
Reg. EINECS number
Smiles
Reg. EC number232-203-7
ChemSpider

Content

Getting

  • The action of iodine vapor on palladium metal:
Pd+I2→PdI2{\ displaystyle {\ mathsf {Pd + I_ {2} \ {\ xrightarrow {}} \ PdI_ {2}}}}  
  • The effect of potassium iodide on palladium (II) chloride :
PdCl2+2KI→PdI2+2KCl{\ displaystyle {\ mathsf {PdCl_ {2} + 2KI \ {\ xrightarrow {}} \ PdI_ {2} + 2KCl}}}  

Physical Properties

Palladium (II) iodide forms dark red crystals, does not dissolve in water, dissolves in hydroiodic acid and iodide solutions.

Chemical Properties

  • Decomposes on heating:
PdI2→TPd+I2{\ displaystyle {\ mathsf {PdI_ {2} \ {\ xrightarrow {T}} \ Pd + I_ {2}}}}  
  • It is soluble in hydroiodic acid:
PdI2+2HI→H2[PdIfour]{\ displaystyle {\ mathsf {PdI_ {2} + 2HI \ {\ xrightarrow {}} \ H_ {2} [PdI_ {4}]}}}  

Literature

  • Chemical Encyclopedia / Editorial Board: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1992. - T. 3. - 639 p. - ISBN 5-82270-039-8 .
  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1972. - T. 2. - 871 p.



Source - https://ru.wikipedia.org/w/index.php?title=Palladium iodide ( II)&oldid = 85502009


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