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Rhodium (III) Fluoride

Rhodium (III) fluoride is an inorganic compound, a salt of a metal of rhodium and hydrofluoric acid with the formula RhF 3 , red crystals, does not dissolve in water.

Rhodium fluoride
Are common
Systematic
name
Rhodium (III) Fluoride
Traditional namesRhodium fluoride
Chem. formulaRhf 3
Physical properties
conditionred crystals
Molar mass159.95 g / mol
Density5.38 g / cm³
Thermal properties
T. sub.600 ° C
Classification
Reg. CAS number
PubChem
Smiles
Inchi
ChemSpider

Getting

  • The effect of fluoride on heated rhodium:
2Rh+3F2→500-600oC2Rh F 3{\ displaystyle {\ mathsf {2Rh + 3F_ {2} \ {\ xrightarrow {500-600 ^ {o} C}} \ 2RhF_ {3}}}}  

Physical Properties

Rhodium (III) fluoride forms red crystals of trigonal syngony , space group R 3 c , cell parameters a = 0.4878 nm , c = 0.6809 nm , Z = 3 (according to other sources, these are crystals of rhombic syngony , cell parameters a = 0.530 nm , b = 0.719 nm , c = 0.487 nm , Z = 4 ).

It is not soluble in water, acids and alkalis.

Literature

  • Handbook of a chemist / Editorial: Nikolsky B.P. et al. - 2nd ed., Rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Handbook of a chemist / Editorial: Nikolsky B.P. et al. - 3rd ed., Rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1972. - T. 2. - 871 p.



Source - https://ru.wikipedia.org/w/index.php?title= Rhodium fluoride ( III)&oldid = 80372523


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