Dicarbonylruthenium Diiodide

Dicarbonylruthenium Diiodide
Dicarbonylruthenium Diiodide
General
Systematic ; name	Dicarbonylruthenium Diiodide
Chem. formula	Ru (CO) 2 I 2
Physical properties
condition	brown or red-yellow crystals
Molar mass	410.90 g / mol

Dicarbonylruthenium diiodide is an inorganic compound, a carbonyl complex of ruthenium with the formula Ru (CO) ₂ I ₂ , brown or red-yellow crystals, does not dissolve in water.

Content

1 Receiving
2 Physical properties
3 Chemical properties
4 Literature

Getting

The reaction of nonacarbonylruthenium with iodine :

{\mathsf {Ru_{2}(CO)_{9}+2I_{2}\ {\xrightarrow {}}\ 2Ru(CO)_{2}I_{2}+2CO}}

{\ displaystyle {\ mathsf {Ru_ {2} (CO) _ {9} + 2I_ {2} \ {\ xrightarrow {}} \ 2Ru (CO) _ {2} I_ {2} + 2CO}}}

The effect of carbon monoxide on ruthenium (III) iodide :

{\mathsf {2RuI_{3}+4CO\ {\xrightarrow {}}\ 2Ru(CO)_{2}I_{2}+I_{2}}}

{\ displaystyle {\ mathsf {2RuI_ {3} + 4CO \ {\ xrightarrow {}} \ 2Ru (CO) _ {2} I_ {2} + I_ {2}}}}

Physical Properties

Dicarbonylruthenium diiodide forms diamagnetic brown or red-yellow crystals.

Insoluble in water and organic solvents.

Chemical Properties

Reacts with potassium cyanide :

{\mathsf {Ru(CO)_{2}I_{2}+2KCN\ {\xrightarrow {}}\ K_{2}[Ru(CO)_{2}(CN)_{2}I_{2}]}}

{\ displaystyle {\ mathsf {Ru (CO) _ {2} I_ {2} + 2KCN \ {\ xrightarrow {}} \ K_ {2} [Ru (CO) _ {2} (CN) _ {2} I_ {2}]}}}

Literature

Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1972. - T. 2. - 871 p.