Cobalt phosphides

Cobalt phosphides - inorganic compounds of cobalt and phosphorus metal, black or gray crystals.

Properties of cobalt phosphides
Composition	Like weight	The properties	Getting
Co ₂ P	148.84	d = 6.4 g / cm³, T _pl. = 1384, gray crystals rhombic syngony , space group P nma , cell parameters a = 0.567 nm, b = 0.3520 nm, c = 0.5638 nm, Z = 4	${\mathsf {4Co+2PI_{3}\ {\xrightarrow {T}}\ 2Co_{2}P+3I_{2}}}$ ${\ displaystyle {\ mathsf {4Co + 2PI_ {3} \ {\ xrightarrow {T}} \ 2Co_ {2} P + 3I_ {2}}}}$ ${\ displaystyle {\ mathsf {4Co + 2PI_ {3} \ {\ xrightarrow {T}} \ 2Co_ {2} P + 3I_ {2}}}}$
Co ₃ P ₂	238.75	black powder	${\mathsf {3CoCl_{2}+2PH_{3}\ {\xrightarrow {T}}\ Co_{3}P_{2}+6HCl}}$ ${\ displaystyle {\ mathsf {3CoCl_ {2} + 2PH_ {3} \ {\ xrightarrow {T}} \ Co_ {3} P_ {2} + 6HCl}}}$ ${\ displaystyle {\ mathsf {3CoCl_ {2} + 2PH_ {3} \ {\ xrightarrow {T}} \ Co_ {3} P_ {2} + 6HCl}}}$
Co ₄ P ₃	328.65	black powder	${\mathsf {4Co+3P\ {\xrightarrow {500^{o}C}}\ 2Co_{4}P_{3}}}$ ${\ displaystyle {\ mathsf {4Co + 3P \ {\ xrightarrow {500 ^ {o} C}} \ 2Co_ {4} P_ {3}}}}$ ${\ displaystyle {\ mathsf {4Co + 3P \ {\ xrightarrow {500 ^ {o} C}} \ 2Co_ {4} P_ {3}}}}$
Co ₂ P ₃	210.79	black crystals
CoP	89.91	black crystals of rhombic syngony , space group P nma , cell parameters a = 0.5066 nm, b = 0.3274 nm, c = 0.5588 nm, Z = 4
CoP ₂	120.88
CoP ₃	151.85

Literature

Chemical Encyclopedia / Editorial Board: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1990. - T. 2. - 671 p. - ISBN 5-82270-035-5 .
Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1972. - T. 2. - 871 p.