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Tungsten arsenide

Tungsten arsenide is an inorganic compound of tungsten metal and arsenic with the formula WAs 2 , black crystals, insoluble in water.

Tungsten arsenide
Are common
Systematic
name
Tungsten arsenide
Traditional namesArsenic Tungsten
Chem. formulaWAs 2
Physical properties
conditionblack crystals
Molar mass333,69 g / mol
Density6.9 g / cm³

Getting

  • The interaction of pure substances:
W+2As→620oCWAs2{\ displaystyle {\ mathsf {W + 2As \ {\ xrightarrow {620 ^ {o} C}} \ WAs_ {2}}}} {\displaystyle {\mathsf {W+2As\ {\xrightarrow {620^{o}C}}\ WAs_{2}}}}
  • Reaction of arsine and tungsten (VI) chloride :
WCl6+2AsH3→350oCWAs2+6HCl{\ displaystyle {\ mathsf {WCl_ {6} + 2AsH_ {3} \ {\ xrightarrow {350 ^ {o} C}} \ WAs_ {2} + 6HCl}}} {\displaystyle {\mathsf {WCl_{6}+2AsH_{3}\ {\xrightarrow {350^{o}C}}\ WAs_{2}+6HCl}}}

Physical Properties

Tungsten arsenide forms black crystals that are insoluble in water.

Chemical Properties

  • It oxidizes when heated in air:
WAs2+3O2→TWO3+As2O3{\ displaystyle {\ mathsf {WAs_ {2} + 3O_ {2} \ {\ xrightarrow {T}} \ WO_ {3} + As_ {2} O_ {3}}}} {\displaystyle {\mathsf {WAs_{2}+3O_{2}\ {\xrightarrow {T}}\ WO_{3}+As_{2}O_{3}}}}

Literature

  • Chemist Handbook / Redkol .: Nikolsky B.P. et al. - 3rd ed., Rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Ripan R., Chetyanu I. Inorganic chemistry. Metal Chemistry. - M .: Mir, 1972. - T. 2. - 871 p.
  • JB Taylor, LD Calvert, MR Hunt. The arsenides of tungsten and molybdenum: WAs 2 , W 2 As 3 , MoAs 2 , Mo 2 As 3 , and Mo 5 As 4 // Canadian Journal of Chemistry . - 1965. - V. 43 , no. 11 - p . 3044-3051 . - DOI : 10.1139 / v65-419 .

See also

▼ Tungsten compounds
► Tungsten compounds alphabetically
► Tungsten borides
► Tungstates
► Tungsten intermetallic compounds
► Tungsten carbide
► Carbonyl tungsten complexes
► Minerals of tungsten
► Tungsten nitrides
► Tungsten oxides
► Tungsten Silicides
► Tungsten salt
► Tungsten phosphides
  Tungsten arsenide
  Ferro Tungsten


Source - https://ru.wikipedia.org/w/index.php?title=Arsenide_tungra && idid = 96172073


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Clever Geek | 2019