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Molybdenum acid

Molybdenum acid is an inorganic compound, an oxygen-containing acid formed by a molybdenum metal with the formula H 2 MoO 4 , colorless (white) crystals, slightly soluble in water, forms crystalline hydrates .

Molybdenum acid
Are common
Systematic
name
Molybdenum acid
Chem. formulaH 2 MoO 4
Physical properties
conditioncolorless (white) crystals
Molar mass161.95 g / mol
Density3.112 g / cm³
Thermal properties
T. melt.decomp. 115 ° C
Chemical properties
Solubility in water0.12 20 ; 2.3 70 g / 100 ml
Classification
Reg. CAS number7782-91-4
PubChem
Reg. EINECS number
Smiles
Inchi
Reg. EC number231-970-5
Chebi
ChemSpider

Content

Getting

  • Crystalline hydrate is formed by the action of dilute acids on concentrated solutions of alkali metal molybdates:
Na2MoOfour+2HCl+H2O→60-70oCH2MoOfour⋅H2O↓+2NaCl{\ displaystyle {\ mathsf {Na_ {2} MoO_ {4} + 2HCl + H_ {2} O \ {\ xrightarrow {60-70 ^ {o} C}} \ H_ {2} MoO_ {4} \ cdot H_ {2} O \ downarrow + 2NaCl}}}  
  • Anhydrous acid is obtained by concentration of an aqueous solution of H 2 MoO 4 • H 2 O at 40-70 ° C.

Physical Properties

Molybdenum acid forms colorless (white) crystals, slightly soluble in water.

Forms crystalline hydrates of the composition H 2 MoO 4 • n H 2 O, where n = 1 and 2.

Chemical Properties

  • Forms salts - molybdates :
H2MoOfour+2NaOH→Na2MoOfour+2H2O{\ displaystyle {\ mathsf {H_ {2} MoO_ {4} + 2NaOH \ {\ xrightarrow {}} \ Na_ {2} MoO_ {4} + 2H_ {2} O}}}  

Other connections

Molybdenum acids of a different composition are known:

  • Dimolybdenum acid H 2 Mo 2 O 7 or 2MoO 3 • H 2 O
  • tetramolybdic acid H 2 Mo 4 O 13 or 4MoO 3 • H 2 O
  • mesomolybdic acid H 4 MoO 5 or MoO 3 • 2H 2 O
  • orthomolybdic acid H 6 MoO 6 or MoO 3 • 3H 2 O

Literature

  • Chemical Encyclopedia / Editorial Board: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1992. - T. 3. - 639 p. - ISBN 5-82270-039-8 .
  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.
  • Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1972. - T. 2. - 871 p.



Source - https://ru.wikipedia.org/w/index.php?title=Molybdenum acid&oldid = 85818639


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