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Vanadium Disulfide

Vanadium disulfide is a binary inorganic compound, a metal salt of vanadium and hydrogen sulfide with the formula VS 2 , a brown powder, insoluble in water.

Vanadium Disulfide
General
Systematic
name
Vanadium Disulfide
Traditional namesVanadium Sulfur
Chem. formulaVS 2
Physical properties
conditionbrown powder
Molar mass115.07 g / mol
Density3.2 g / cm³
Classification
Reg. CAS number
PubChem
Smiles
Inchi
ChemSpider

Getting

  • Addition of acid to a solution of tetravalent vanadium salts and ammonium sulfide :
VClfour+2(NHfour)2S+2H2SOfour→VS2↓+2(NHfour)2SOfour+fourHCl{\ displaystyle {\ mathsf {VCl_ {4} +2 (NH_ {4}) _ {2} S + 2H_ {2} SO_ {4} \ {\ xrightarrow {}} \ VS_ {2} \ downarrow +2 ( NH_ {4}) _ {2} SO_ {4} + 4HCl}}}  

Physical Properties

Vanadium disulfide forms brown trigonal crystal crystals, space group P 3 m1 , cell parameters a = 0.3348 nm, c = 0.6122 nm, Z = 1.

Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1972. - T. 2. - 871 p.


Source - https://ru.wikipedia.org/w/index.php?title= Vanadium disulfide&oldid = 80364641


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