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Yttrium hexaboride

Yttrium hexaboride is a binary inorganic compound of yttrium and boron metal with the formula YB 6 , dark blue crystals.

Yttrium hexaboride
Are common
Systematic
name
Yttrium hexaboride
Chem. formulaYb 6
Physical properties
conditiondark blue crystals
Molar mass153.77 g / mol
Density3.72 g / cm³
Thermal properties
T. melt.2600 ° C
Classification
Reg. CAS number12008-32-1
Reg. EINECS number

Content

Getting

  • Electrolysis of the melt Y 2 O 3 • 2 B 2 O 3 with the addition of magnesium oxide and fluoride (ratio 1:15). For electrolysis, platinum , tungsten and molybdenum cathodes are used.

Physical Properties

Yttrium hexaboride forms dark blue crystals of cubic syngony , space group P m3m , cell parameters a = 0.408 nm, Z = 1.

Chemical Properties

Yttrium boride is soluble in hot concentrated sulfuric acid , in conc. nitric acid at 0 ° C. It also interacts with melts of alkali, carbonates and nitrates of alkali metals .

Literature

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1972. - T. 2. - 871 p.
  • CRC Handbook of Chemistry and Physics . - 89th Edition. - Taylor and Francis Group, LLC, 2008-2009.


Source - https://ru.wikipedia.org/w/index.php?title= Yttria hexaboride&oldid = 80952255


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Clever Geek | 2019