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Tetraphenyl lead

Tetraphenyl lead - organoelemental substance , the simplest aryl derivative of lead metal with the formula Pb (C 6 H 5 ) 4 , colorless crystals, insoluble in water.

Tetraphenyl lead
Are common
Systematic
name
Tetraphenyl lead
Chem. formulaC₂₄H₂₀Pb
Rac formulaPb (C 6 H 5 ) 4
Physical properties
conditioncolorless crystals
Molar mass515.61 g / mol
Density1,5298 g / cm³
Thermal properties
T. melt.225 ° C
T. Kip.240 15 mm Hg ° C
Classification
Reg. CAS number
Pubchem
Reg. EINECS number
SMILES
Inchi
CHEBI
Chemspider
Security
Toxicityis poisonous

Getting

  • Reaction of lead (or an alloy with 6-10% sodium ) with bromobenzene :
3Pb+fourC6HfiveBr→Pb(C6Hfive)four+2PbBr2{\ displaystyle {\ mathsf {3Pb + 4C_ {6} H_ {5} Br \ {\ xrightarrow {}} \ Pb (C_ {6} H_ {5}) _ {4} + 2PbBr_ {2}}}} {\displaystyle {\mathsf {3Pb+4C_{6}H_{5}Br\ {\xrightarrow {}}\ Pb(C_{6}H_{5})_{4}+2PbBr_{2}}}}
  • The effect of the Grignard reagent on lead (II) chloride :
2PbCl2+fourC6HfiveMgBr→Pb(C6Hfive)four+fourMgBrCl+Pb{\ displaystyle {\ mathsf {2PbCl_ {2} + 4C_ {6} H_ {5} MgBr \ {\ xrightarrow {}} \ Pb (C_ {6} H_ {5}) _ {4} + 4MgBrCl + Pb}} } {\displaystyle {\mathsf {2PbCl_{2}+4C_{6}H_{5}MgBr\ {\xrightarrow {}}\ Pb(C_{6}H_{5})_{4}+4MgBrCl+Pb}}}

Physical Properties

Tetraphenyl lead forms colorless tetragonal crystals, space group P 4 2 1 c , cell parameters a = 1.730 nm, c = 0.645 nm, Z = 4.

Chemical Properties

  • Reacts with glacial acetic acid :
Pb(C6Hfive)four+fourCH3COOH→Pb(CH3COO)four+fourC6H6{\ displaystyle {\ mathsf {Pb (C_ {6} H_ {5}) _ {4} + 4CH_ {3} COOH \ {\ xrightarrow {}} \ Pb (CH_ {3} COO) _ {4} + 4C_ {6} H_ {6}}}} {\displaystyle {\mathsf {Pb(C_{6}H_{5})_{4}+4CH_{3}COOH\ {\xrightarrow {}}\ Pb(CH_{3}COO)_{4}+4C_{6}H_{6}}}}

Literature

  • Chemical Encyclopedia / Redkol .: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1995. - Vol. 4. - 639 p. - ISBN 5-82270-092-4 .
  • Chemist Handbook / Redkol .: Nikolsky B.P. et al. - 2nd ed., Rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Ripan R., Chetyanu I. Inorganic chemistry. Metal Chemistry. - M .: Mir, 1971. - T. 1. - 561 p.



Source - https://ru.wikipedia.org/w/index.php?title=Tetrafexyl lead&oldid = 100141115


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