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Tetraethyl germanium

Tetraethyl germanium is an organoelement substance , the simplest alkyl derivative of germanium with the formula Ge (C 2 H 5 ) 4 , a colorless liquid.

Tetraethyl germanium
Tetraethylgermanium.svg
Are common
Systematic
name
Tetraethyl germanium
Chem. formulaGe (C 2 H 5 ) 4
Physical properties
conditioncolorless liquid
Molar mass188.88 g / mol
Density0.991 g / cm³
Thermal properties
T. melt.-90 ° C
T. bale.163 ° C
Classification
Reg. CAS number597-63-7
PubChem
Reg. EINECS number
Smiles
Inchi
Reg. EC number209-905-7
RTECSLY5290000
UN number
ChemSpider

Getting

  • The reaction of germanium chloride with diethylzinc :
GeClfour+2Zn(C2Hfive)2→Ge(C2Hfive)four+2ZnCl2{\ displaystyle {\ mathsf {GeCl_ {4} + 2Zn (C_ {2} H_ {5}) _ {2} \ {\ xrightarrow {}} \ Ge (C_ {2} H_ {5}) _ {4} + 2ZnCl_ {2}}}}  
  • Heating germanium with ethyl chloride in the presence of copper :
Ge+fourC2HfiveCl+2Cu→Ge(C2Hfive)four+2CuCl2{\ displaystyle {\ mathsf {Ge + 4C_ {2} H_ {5} Cl + 2Cu \ {\ xrightarrow {}} \ Ge (C_ {2} H_ {5}) _ {4} + 2CuCl_ {2}}} }  
  • The effect of Grignard reagent on germanium (IV) chloride :
GeClfour+fourC2HfiveMgBr→Ge(C2Hfive)four+2MgCl2+2MgBr2{\ displaystyle {\ mathsf {GeCl_ {4} + 4C_ {2} H_ {5} MgBr \ {\ xrightarrow {}} \ Ge (C_ {2} H_ {5}) _ {4} + 2MgCl_ {2} + 2MgBr_ {2}}}}  

Physical Properties

Tetraethyl germanium is a colorless liquid.

Literature

  • Chemical Encyclopedia / Editorial Board: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1988. - T. 1. - 623 p.
  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1971. - T. 1. - 561 p.
Germanium compound classes
► Germany compounds


Source - https://ru.wikipedia.org/w/index.php?title=Tetraethylgermanium&oldid=80383159


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Clever Geek | 2019