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Lithium Metagermanate

Lithium meta- germanate is an inorganic compound, a salt of lithium metal and meta-germanium acid with the formula Li 2 GeO 3 , colorless crystals, slightly soluble in water, forms a crystalline hydrate .

Lithium Metagermanate
Are common
Systematic
name
Lithium Metagermanate
Traditional namesLithium germanic acid
Chem. formulaLi 2 GeO 3
Physical properties
Molar mass134.52 g / mol
Density3.53 g / cm³
Thermal properties
T. melt.1239 ° C
Chemical properties
Solubility in water0.84 g / 100 ml
Optical properties
Refractive index1.7
Classification
Reg. CAS number
PubChem
Reg. EINECS number
Smiles
Inchi
ChemSpider

Getting

  • Fusion of germanium oxide (IV) and lithium carbonate :
GeO2+Li2CO3→TLi2GeO3+CO2↑{\ displaystyle {\ mathsf {GeO_ {2} + Li_ {2} CO_ {3} \ {\ xrightarrow {T}} \ Li_ {2} GeO_ {3} + CO_ {2} \ uparrow}}}  
  • Exchange reaction:
Na2GeO3+2LiCl→Li2GeO3⋅one/3H2O↓+2NaCl{\ displaystyle {\ mathsf {Na_ {2} GeO_ {3} + 2LiCl \ {\ xrightarrow {}} \ Li_ {2} GeO_ {3} \ cdot 1 / 3H_ {2} O \ downarrow + 2NaCl}}}  

Physical Properties

Lithium meta-germanate forms colorless crystals. cubic system , cell parameters a = 0.6795 nm. There is evidence of other structures: hexagonal ( a = 0.554 nm, c = 0.480 nm), tetragonal ( a = 0.480 nm, c = 0.277 nm), rhombic ( a = 0.960 nm, b = 0.554 nm, c = 0.480 nm) .

Forms a crystalline hydrate of the composition Li 2 GeO 3 • 1 / 3H 2 O.

Literature

  • Chemical Encyclopedia / Editorial Board: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1988. - T. 1. - 623 p.
  • Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1971. - T. 1. - 561 p.
  • Tanaev I.V., Shpirt M. Ya. Chemistry of Germany. - M .: Chemistry, 1967 .-- 452 p.
Germanium compound classes
► Germany compounds


Source - https://ru.wikipedia.org/w/index.php?title=Lithium metagermanate&oldid = 80366210


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Clever Geek | 2019