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Triphenilindinium

Triphenylindinium is an organometallic substance , arene derivative of indium with the formula In (C 6 H 5 ) 3 , colorless crystals.

Triphenilindinium
Are common
Systematic
name
Triphenilindinium
Chem. formulaIn (C 6 H 5 ) 3
Physical properties
conditioncolorless crystals
Molar mass346.13 g / mol
Thermal properties
T. melt.208 ° C
Classification
Reg. CAS number3958-47-2

Content

Getting

  • Interaction of indium with diphenylmercury :
2In+3Hg(C6Hfive)2→2In(C6Hfive)3+3Hg{\ displaystyle {\ mathsf {2In + 3Hg (C_ {6} H_ {5}) _ {2} \ {\ xrightarrow {}} \ 2In (C_ {6} H_ {5}) _ {3} + 3Hg} }}  

Physical Properties

Triphenylindinium is a colorless crystal.

Chemical Properties

  • Reacts with water:
In(C6Hfive)3+H2O→In(C6Hfive)2OH+C6H6{\ displaystyle {\ mathsf {In (C_ {6} H_ {5}) _ {3} + H_ {2} O \ {\ xrightarrow {}} \ In (C_ {6} H_ {5}) _ {2 } OH + C_ {6} H_ {6}}}}  
  • Reacts with bromine :
In(C6Hfive)3+Br2→InBr(C6Hfive)2+C6HfiveBr{\ displaystyle {\ mathsf {In (C_ {6} H_ {5}) _ {3} + Br_ {2} \ {\ xrightarrow {}} \ InBr (C_ {6} H_ {5}) _ {2} + C_ {6} H_ {5} Br}}}  
In(C6Hfive)3+2Br2→InBr2(C6Hfive)+2C6HfiveBr{\ displaystyle {\ mathsf {In (C_ {6} H_ {5}) _ {3} + 2Br_ {2} \ {\ xrightarrow {}} \ InBr_ {2} (C_ {6} H_ {5}) + 2C_ {6} H_ {5} Br}}}  

Literature

  • Chemical Encyclopedia / Editorial Board: Knunyants I.L. et al. - M .: Soviet Encyclopedia, 1990. - T. 2. - 671 p. - ISBN 5-82270-035-5 .
  • Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1971. - T. 1. - 561 p.



Source - https://ru.wikipedia.org/w/index.php?title=Triphenilindia&oldid=91271233


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Clever Geek | 2019