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Indium nitride

Indium nitride ( InN ) - a binary inorganic compound of indium metal and nitrogen with the formula InN, black crystals.

Indium nitride
General
Systematic
name
Indium nitride (III)
Chem. formulaInn
Physical properties
conditionblack crystals
Molar mass128.83 g / mol
Density6.86-6.91 g / cm³
Classification
Reg. CAS number25617-98-5
PubChem
Reg. EINECS number
Smiles
Inchi
ChemSpider

Content

  • 1 Receiving
  • 2 Physical properties
  • 3 Application
  • 4 Lite [1]
  • 5 notes

Getting

  • Decomposition of complex sodium hexafluoroindiate in an ammonia atmosphere:
Na3[InF6]+NH3→600oCInN+3NaF+3HF{\ displaystyle {\ mathsf {Na_ {3} [InF_ {6}] + NH_ {3} \ {\ xrightarrow {600 ^ {o} C}} \ InN + 3NaF + 3HF}}}  
  • Decomposition of ammonium hexafluoroindiate :
(NHfour)3[InF6]→600oCInN+2NHfourF+fourHF{\ displaystyle {\ mathsf {(NH_ {4}) _ {3} [InF_ {6}] \ {\ xrightarrow {600 ^ {o} C}} \ InN + 2NH_ {4} F + 4HF}}}  

Physical Properties

Indium nitride forms black diamagnetic crystals of hexagonal syngony , space group P 6mc , cell parameters a = 0.3533 nm, c = 0.5692 nm, Z = 2.

A semiconductor with a band gap of the order of ~ 0.7 eV, depending on temperature. At temperatures below 4 K, it is a superconductor .

Application

Indium nitride is added to gallium nitride in the production of ultraviolet, blue LEDs . It is also promising as a material for solar panels, with the utilization of light with a wavelength of up to 1900 nm.

Lite [1] Rathura

  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1971. - T. 1. - 561 p.

Notes

  1. ↑ T. Inushima, VV Mamutin, et al. [J. Crystal. Growth, 227/228, 481-485, 2001. Physical properties of InN with band gap lower than 1.0 eV.] (English) // Proc. of XI-th Intern.Conf. on MBE, Beijing, 2000. - 2000. - September 1 ( No. 227/228 ). - S. 481-485 .


Source - https://ru.wikipedia.org/w/index.php?title=Nitrid_indium&oldid=89443046


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