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Strontium carbide

Strontium carbide is a binary inorganic compound of strontium and carbon with the formula SrС 2 , black crystals.

Strontium carbide
General
Systematic
name
Strontium carbide
Traditional namesCarbon strontium
Chem. formulaSrC 2
Rat formulaSrc 2
Physical properties
Molar mass111.64 g / mol
Density3.2; 3.26 g / cm³
Thermal properties
T. melt.≈ 1800 ° C

Content

  • 1 Receiving
  • 2 Physical properties
  • 3 Chemical properties
  • 4 Literature

Getting

  • Sintering of strontium oxide or carbonate with coal :
SrO+3C→>ToCSrC2+CO{\ displaystyle {\ mathsf {SrO + 3 \ C \ {\ xrightarrow {> T ^ {o} C}} \ SrC_ {2} + CO}}}  
SrCO3+3C→>ToCSrC2+CO+CO2{\ displaystyle {\ mathsf {SrCO_ {3} +3 \ C \ {\ xrightarrow {> T ^ {o} C}} \ SrC_ {2} + CO + CO_ {2}}}}  

Physical Properties

Strontium carbide forms tetragonal crystals, space group I 4 / mmm , cell parameters a = 0.411 nm, c = 0.668 nm, Z = 2.

Chemical Properties

  • Strontium carbide reacts when heated with halogens , oxygen , nitrogen :
SrC2+Cl2→ToCSrCl2+2C{\ displaystyle {\ mathsf {SrC_ {2} + Cl_ {2} \ {\ xrightarrow {T ^ {o} C}} \ SrCl_ {2} +2 \ C}}}  
2SrC2+3O2→ToC2SrO+fourCO{\ displaystyle {\ mathsf {2 \ SrC_ {2} +3 \ O_ {2} \ {\ xrightarrow {T ^ {o} C}} \ 2 \ SrO + 4 \ CO}}}  
SrC2+N2→ToCSrCN2+C{\ displaystyle {\ mathsf {SrC_ {2} + N_ {2} \ {\ xrightarrow {T ^ {o} C}} \ SrCN_ {2} + C}}}  
  • Interacts with water:
SrC2+2H2O→Sr(OH)2+H2C2↑{\ displaystyle {\ mathsf {SrC_ {2} +2 \ H_ {2} O \ {\ xrightarrow {\}} \ Sr (OH) _ {2} + H_ {2} C_ {2} \ uparrow}}}  
  • and acids
SrC2+2HCl→SrCl2+H2C2↑{\ displaystyle {\ mathsf {SrC_ {2} +2 \ HCl \ {\ xrightarrow {\}} \ SrCl_ {2} + H_ {2} C_ {2} \ uparrow}}}  

Literature

  • Ripan R., Chetyanu I. Inorganic chemistry. Chemistry of metals. - M .: Mir, 1971. - T. 1. - 561 p.
  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 2nd ed., rev. - M.-L.: Chemistry, 1966. - T. 1. - 1072 p.
  • Chemistry Handbook / Editorial: Nikolsky B.P. et al. - 3rd ed., rev. - L .: Chemistry, 1971. - T. 2. - 1168 p.


Source - https://ru.wikipedia.org/w/index.php?title=Strontium carbide&oldid = 100063134


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