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Calcium cyanamide

Calcium cyanamide is a calcium salt of cyanic acid amide ( cyanamide ) with the formula CaCN 2 .

Calcium cyanamide
Calcium cyanamide.png
Are common
Systematic
name
Calcium cyanamide
Chem. formulaCaCN 2
Physical properties
conditionColorless crystals
Molar mass80.10 g / mol
Density2.29 g / cm³
Thermal properties
T. melt.1340 ° C
Steam pressure
Classification
Reg. CAS number156-62-7
PubChem
Reg. EINECS number
Smiles
Inchi
Reg. EC number205-861-8
RTECSGS6000000
Chebi
UN number
ChemSpider

Content

Getting

For the synthesis of calcium cyanamide, calcium carbide is sintered with carbon in a nitrogen atmosphere [2] :

CaC2+N2→CaCN2+C{\ displaystyle {\ mathsf {CaC_ {2} + N_ {2} \ rightarrow CaCN_ {2} + C}}}  

Properties

Technical calcium cyanamide - colorless crystals that do not decompose in dry air. Contains approximately 20% bound nitrogen . Actually, for the sake of binding atmospheric nitrogen, this substance is obtained. Further, for example, ammonia can be obtained by heating calcium cyanamide with water :

CaCN2+3H2O→2NH3+CaCO3{\ displaystyle {\ mathsf {CaCN_ {2} + 3H_ {2} O \ rightarrow 2NH_ {3} + CaCO_ {3}}}}  

Application

As a component of phytotoxic weapons and nitrogen fertilizer [3] .

Notes

  1. ↑ http://www.cdc.gov/niosh/npg/npgd0091.html
  2. ↑ Inorganic chemistry / Yu. D. Tretyakov / 2 volume, 2nd edition
  3. ↑ The use of calcium cyanamide as a nitrogen fertilizer "Agrochemistry in agriculture

Literature

  • Ter-Gazaryan G.G. Fixation of atmospheric nitrogen. - State Planning Commission of the ZSFSR, 1926


Source - https://ru.wikipedia.org/w/index.php?title= Calcium cyanamide&oldid = 80413153


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Clever Geek | 2019