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Antimony acid

Antimony acid is an inorganic compound of antimony oxide and water. Antimony acid exists in solution in several forms, for example, hexahydroximony H [Sb (OH) 6 ]. Upon precipitation, a gel with a variable water content is obtained; with prolonged drying, insoluble metasimic acid HSbO 3 is obtained. Salts of antimony acid are called antimonates (antimoniates) or oxystibates .

Getting

  • Nitric acid oxidation:
3Sb+fiveHNO3→3HSbO3+fiveNO↑+H2O{\ displaystyle {\ mathsf {3Sb + 5HNO_ {3} \ {\ xrightarrow {\}} 3HSbO_ {3} + 5NO \ uparrow + H_ {2} O}}}  
  • By the interaction of its salts with acids:
K[Sb(OH)6]+HCl→H[Sb(OH)6]+KCl{\ displaystyle {\ mathsf {K [Sb (OH) _ {6}] + HCl \ {\ xrightarrow {\}} H [Sb (OH) _ {6}] + KCl}}}  

Chemical Properties

  • Reacts with alkalis:
H[Sb(OH)6]+NaOH→Na[Sb(OH)6]+H2O{\ displaystyle {\ mathsf {H [Sb (OH) _ {6}] + NaOH \ rightarrow Na [Sb (OH) _ {6}] + H_ {2} O}}}  

Derivatives

Antimony acid salts are called antimonates, for example:

  • Lead Antimonate (II)


Source - https://ru.wikipedia.org/w/index.php?title= Antimony acid &oldid = 96660995


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